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Overexpression of Cx43 inhibits G1 to S phase progression 20,21,22,23,24 , extends the duration of mitosis, and blocks G1 phase 25

Enlargement of the ring system of 23 , by oxidatative cyclization of Hcy 1 /Hcy 3 side chains rather than the Hcy 1 /Cys 3 side chains of 23 resulted in a compound comprising a 14-membered macrocycle but with a somewhat lower affinity to IRAP (Ki = 5.1 nM), vide infra

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